Thickness control in electrophoretic deposition of WO3 nanofiber thin films for solar water splitting

Yuanxing Fang, Wei Cheat Lee, Giacomo E. Canciani, Thomas C. Draper, Zainab F. Al-Bawi, Jasbir S. Bedi, Christopher C. Perry, Qiao Chen

Research output: Contribution to journalArticlepeer-review

Abstract

Electrophoretic deposition (EPD) of ground electrospun WO3 nanofibers was applied to create photoanodes with controlled morphology for the application of photoelectrochemical (PEC) water splitting. The correlations between deposition parameters and film thicknesses were investigated with theoretical models to precisely control the morphology of the nanostructured porous thin film. The photoconversion efficiency was further optimized as a function of film thickness. A maximum photoconversion efficiency of 0.924% from electrospun WO3 nanofibers that EPD deposited on a substrate was achieved at a film thickness of 18 μm.

Original languageEnglish
Article number13793
Pages (from-to)39-45
Number of pages7
JournalMaterials Science and Engineering B: Solid-State Materials for Advanced Technology
Volume202
DOIs
StatePublished - Dec 1 2015

ASJC Scopus Subject Areas

  • General Materials Science
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Keywords

  • Electrophoretic deposition
  • Electrospinning
  • Photoelectrochemical water splitting
  • Thickness
  • WO nanofiber

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