A functional model related to cytochrome c oxidase and its electrocatalytic four-electron reduction of O2

James P. Collman; Lei Fu; Paul C. Herrmann; Xumu Zhang

doi:10.1126/science.275.5302.949

A functional model related to cytochrome c oxidase and its electrocatalytic four-electron reduction of O₂

James P. Collman, Lei Fu, Paul C. Herrmann, Xumu Zhang

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	949-951
Number of pages	3
Journal	Science
Volume	275
Issue number	5302
DOIs	https://doi.org/10.1126/science.275.5302.949
State	Published - Feb 14 1997
Externally published	Yes

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@article{d63f0579b8a64035bffcdb2282c0d8e7,

title = "A functional model related to cytochrome c oxidase and its electrocatalytic four-electron reduction of O2",

author = "Collman, {James P.} and Lei Fu and Herrmann, {Paul C.} and Xumu Zhang",

note = "A cytochrome c oxidase model that consists of a cobalt(II) porphyrin with a copper(I) triazacyclononane macrocycle fastened on the distal face and an imidazole covalently attached to the proximal face has been synthesized and characterized. Redox titrations with molecular oxygen (O2) and cobaltocene were carried out, and O2 was found to bind irreversibly in a 1:1 ratio to the model compound.",

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AU - Collman, James P.

AU - Fu, Lei

AU - Herrmann, Paul C.

AU - Zhang, Xumu

N1 - A cytochrome c oxidase model that consists of a cobalt(II) porphyrin with a copper(I) triazacyclononane macrocycle fastened on the distal face and an imidazole covalently attached to the proximal face has been synthesized and characterized. Redox titrations with molecular oxygen (O2) and cobaltocene were carried out, and O2 was found to bind irreversibly in a 1:1 ratio to the model compound.

PY - 1997/2/14

Y1 - 1997/2/14

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